Synthesis and low-temperature sintering behavior of sr-doped lanthanum chromite powders

被引:0
|
作者
Wei-Ming, Liu [1 ]
Sheng-Li, Li [1 ]
Shi-Gang, Li [1 ]
Xiao, Wang [1 ]
机构
[1] Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China
关键词
lanthanum chromite; sol-gel; rare-earth; sintering;
D O I
暂无
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
La1-xSrxCrO3 powders were synthesized by a sol-gel method and sintered at a low temperature. The powders and sintered pellets were characterized by XRD, TEM, DSC and SEM. It is found that the mean particle size is below 50nm. The powder with x=0 and 0.1 of single phase of La1-xSrxCrO3, and another phase SrCrO4 appears with x=0.3. Lattice distorts and lattice parameters of lanthanum chromite decrease with increasing Sr content. The sintering process of lanthanum chromite can be divided into two stages: a slow exothermic effect below 1200 degrees C and a quick exothermic effect near 1350 degrees C, corresponding to the primary and intermediate sintering stage, respectively. The relative density of the sintered body (x=0.3) after sintering at 1380 degrees C is 91%, according to the procedure derived from the DSC analysis.
引用
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页码:1061 / 1064
页数:4
相关论文
共 11 条
  • [1] Sol-gel synthesis of lanthanum chromite powder
    Bilger, S
    Blass, G
    Forthmann, R
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1997, 17 (08) : 1027 - 1031
  • [2] Mixed valence state and electrical conductivity of La1-xSrxCrO3
    Liu, XN
    Su, WH
    Lu, Z
    Liu, J
    Pei, L
    Liu, W
    He, LY
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 305 (1-2) : 21 - 23
  • [3] Sintering behavior and mechanism of Sr-doped lanthanum chromites with A site excess composition in air
    Mori, M
    Hiei, Y
    Sammes, NM
    [J]. SOLID STATE IONICS, 1999, 123 (1-4) : 103 - 111
  • [4] Dense sintered conditions and sintering mechanisms for alkaline earth metal (Mg, Ca and Sr)-doped LaCrO3 perovskites under reducing atmosphere
    Mori, M
    Yamamoto, T
    Ichikawa, T
    Takeda, Y
    [J]. SOLID STATE IONICS, 2002, 148 (1-2) : 93 - 101
  • [5] Phase diagram studies in the SrO-Cr2O3-La2O3 system in air and under low oxygen pressure
    Peck, DH
    Miller, M
    Hilpert, K
    [J]. SOLID STATE IONICS, 1999, 123 (1-4) : 59 - 65
  • [6] Hydrothermal synthesis and sintering of lanthanum chromite powders doped with calcium
    Rivas-Vázquez, LP
    Rendón-Angeles, JC
    Rodríguez-Galicia, JL
    Zhu, K
    Yanagisawa, K
    [J]. SOLID STATE IONICS, 2004, 172 (1-4) : 389 - 392
  • [7] Sintering mechanisms in strontium doped lanthanum chromite
    Simner, S
    Hardy, J
    Stevenson, J
    Armstrong, T
    [J]. JOURNAL OF MATERIALS SCIENCE, 1999, 34 (23) : 5721 - 5732
  • [8] Sintering characteristics and thermal expansion behavior of Li-doped lanthanum chromite perovskites depending upon preparation method and Sr doping
    Suda, E
    Pacaud, B
    Seguelong, T
    Takeda, Y
    [J]. SOLID STATE IONICS, 2002, 151 (1-4) : 335 - 341
  • [9] Characteristics of lanthanum strontium chromite prepared by glycine nitrate process
    Yang, YJ
    Wen, TL
    Tu, HY
    Wang, DQ
    Yang, JH
    [J]. SOLID STATE IONICS, 2000, 135 (1-4) : 475 - 479
  • [10] CHEMICAL THERMODYNAMIC CONSIDERATIONS IN SINTERING OF LACRO3-BASED PEROVSKITES
    YOKOKAWA, H
    SAKAI, N
    KAWADA, T
    DOKIYA, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (04) : 1018 - 1027