Synthesis of chlorophyll-a derivative inserting an ethynylene group between the carboxylic acid moiety and chlorin π-skeleton and its photosensitizing efficiency in dye-sensitized solar cell

被引：3

作者：

Nakano, Takeo ^{[1
,2
]}

Liu, Yanxiang ^{[3
]}

Wang, Xiao-Feng ^{[3
]}

Tamiaki, Hitoshi ^{[1
]}

机构：

[1] Ritsumeikan Univ, Grad Sch Life Sci, Kusatsu, Shiga 5258577, Japan

[2] Kyushu Univ, Res Ctr Negat Emiss Technol, Nishi Ku, 744 Moto Oka, Fukuoka 8190395, Japan

[3] Jilin Univ, Coll Phys, Minist Educ, Key Lab Phys & Technol Adv Batteries, Changchun 130012, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2022年 / 424卷

关键词：

Chlorophyll; Carboxylic acid; Ethynyl linker; Dye-sensitized solar cell; DFT calculation; OPTICAL-PROPERTIES; OXIDATION;

D O I：

10.1016/j.jphotochem.2021.113633

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A chlorophyll (Chl) derivative inserting an ethynylene group between the carboxy moiety and chlorin it-skeleton was prepared via copper-mediated propargylic alcohol synthesis and phased oxidation reactions from a 3ethynyl-Chl-a derivative. The optical and electrochemical properties were investigated by the measurement of ultraviolet-visible absorption spectra and cyclic voltammograms. Its photosensitizing efficiency in dye-sensitized solar cell was evaluated on a titanium oxide semiconductor, and the effect of the inserting linker was described based on the experimental and theoretical studies.

引用

页数：6

共 9 条

[1] Synthesis and Self-Aggregation of Chlorophyll-a Derivatives with Ethynylene and Phenylene Groups Inserted Between the Hydroxymethyl Group and the Chlorin π-Skeleton
Nakano, Takeo
Tamiaki, Hitoshi
[J]. CHEMPHOTOCHEM, 2020, 4 (05): : 338 - 346
[2] Development of Dye-Sensitized Solar Cells Based on D-π-A Pyridinium Dye without Carboxylic Acid Moiety as Anchoring Group
Ooyama, Yousuke
Yamaguchi, Naoya
Ohshita, Joji
Harima, Yutaka
[J]. ELECTROCHEMISTRY, 2013, 81 (05) : 325 - 327
[3] Molecular engineering on a chlorophyll derivative, chlorin e6, for significantly improved power conversion efficiency in dye-sensitized solar cells
Wang, Xiao-Feng
Tamiaki, Hitoshi
Kitao, Osamu
Ikeuchi, Toshitaka
Sasaki, Shin-ichi
[J]. JOURNAL OF POWER SOURCES, 2013, 242 : 860 - 864
[4] IMPORTANCE OF BINDING STATES BETWEEN PHOTOSENSITIZING MOLECULES AND THE TIO2 SURFACE FOR EFFICIENCY IN A DYE-SENSITIZED SOLAR-CELL
MURAKOSHI, K
KANO, G
WADA, Y
YANAGIDA, S
MIYAZAKI, H
MATSUMOTO, M
MURASAWA, S
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 396 (1-2): : 27 - 34
[5] Synthesis of a carboxylic acid-based ruthenium sensitizer and its applicability towards Dye-Sensitized Solar Cells
Pirashanthan, Arumugam
Thanihaichelvan, Murugathas
Mariappan, Kadarkaraisamy
Velauthapillai, Dhayalan
Ravirajan, Punniamoorthy
Shivatharsiny, Yohi
[J]. SOLAR ENERGY, 2021, 225 : 399 - 406
[6] Synthesis, characterization, electrochemical, spectroelectrochemical and dye-sensitized solar cell properties of Phthalocyanines Containing Carboxylic Acid Anchoring Groups as photosensitizer
Karaoglan, Guelnur Keser
Hisir, Arif
Maden, Yaren Erdag
Karakus, Muecella Ozbay
Koca, Atif
[J]. DYES AND PIGMENTS, 2022, 204
[7] Synthesis and characterization of a binary oxide ZrO2-TiO2 and its application in chlorophyll dye-sensitized solar cell with reduced graphene oxide as counter electrodes
Pai, Asha R.
Nair, Bipin
[J]. BULLETIN OF MATERIALS SCIENCE, 2015, 38 (05) : 1129 - 1133
[8] Synthesis and characterization of a binary oxide ZrO2–TiO2 and its application in chlorophyll dye-sensitized solar cell with reduced graphene oxide as counter electrodes
ASHA R PAI
BIPIN NAIR
[J]. Bulletin of Materials Science, 2015, 38 : 1129 - 1133
[9] Photovoltaic enhancement of dye-sensitized solar cell prepared from [TiO2/ethyl cellulose/terpineol] paste employing TRITON™ X-based surfactant with carboxylic acid group in the oxyethylene chain end
Nam, Jung-Gyu
Lee, Eun-Sung
Jung, Won-Cheol
Park, Young-Jun
Sohn, Byung-Hee
Park, Sang-Cheol
Kim, Joo Sung
Bae, Jin-Young
[J]. MATERIALS CHEMISTRY AND PHYSICS, 2009, 116 (01) : 46 - 51

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