Phosphine-catalyzed highly diastereoselective [3+2] cyclization of isatin derived electron-deficient alkenes with α-allenic esters

被引：108
|
作者：
Zhang, Xiu-Chun [2 ,3 ]
Cao, Shu-Hua [2 ,3 ]
Wei, Yin [1 ]
Shi, Min [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
[2] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[3] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 05期
基金：
中国国家自然科学基金;
关键词：
MORITA-BAYLIS-HILLMAN; 4+2 ANNULATION; ENANTIOSELECTIVE SYNTHESIS; CYCLOADDITION; ALLENOATES; OLEFINS; 2,3-BUTADIENOATES; CYCLOPENTENES; CONSTRUCTION; SUBSTITUTION;
D O I：
10.1039/c0cc04289g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel phosphine-catalyzed highly diastereoselective [3 + 2] cycloaddition of isatin derived alpha,beta-unsaturated ketones with alpha-allenic ester has been developed.
引用
收藏
页码：1548 / 1550
页数：3
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