Direct preparation of vinyl halides from the corresponding ketones and acetyl halides

被引:9
|
作者
Moughamir, K [1 ]
Mezgueldi, B
Atmani, A
Mestdagh, H
Rolando, C
机构
[1] Univ Sidi Mohamed Ben Abdellah, Chim Organ Lab, Fac Sci, Fes 30000, Morocco
[2] IUFM Paris, F-75016 Paris, France
[3] Ecole Normale Super, Dept Chim, F-75231 Paris 05, France
关键词
D O I
10.1016/S0040-4039(98)80019-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Vinyl chlorides and bromides are obtained in good yield from the corresponding ketones and acetyl halides in the presence of trifluoroacetic or trifluoromethanesulfonic acid. The Z isomer is selectively formed. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:59 / 62
页数:4
相关论文
共 50 条
  • [1] FACILE PROCEDURE FOR HYDROLYSIS OF VINYL HALIDES TO KETONES
    MARTIN, SF
    CHOU, TS
    [J]. TETRAHEDRON LETTERS, 1978, (22) : 1943 - 1946
  • [2] The preparation of ketones from acid halides and the Grignard reagent.
    Gilman, H
    Mayhue, ML
    [J]. RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1932, 51 : 47 - 50
  • [3] Direct β-arylation of simple ketones with aryl halides
    Huang, Zhongxing
    Dong, Guangbin
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [4] Fast microwave-assisted preparation of aryl and vinyl nitriles and the corresponding tetrazoles from organo-halides
    Alterman, M
    Hallberg, A
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (23): : 7984 - 7989
  • [5] DIRECT TRANSFORMATION OF METHYL GLYCOPYRANOSIDES INTO CORRESPONDING GLYCOSYL HALIDES
    GRYNKIEWICZ, G
    KONOPKA, M
    [J]. POLISH JOURNAL OF CHEMISTRY, 1987, 61 (1-3) : 149 - 153
  • [6] REACTIONS OF SULFOXIDES WITH ORGANIC HALIDES - PREPARATION OF ALDEHYDES AND KETONES
    NACE, HR
    MONAGLE, JJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (11): : 1792 - 1793
  • [7] COPPER CATALYZED PREPARATION OF VINYL ETHERS FROM UNACTIVATED VINYLIC HALIDES
    KEEGSTRA, MA
    [J]. TETRAHEDRON, 1992, 48 (13) : 2681 - 2690
  • [8] SYNTHESES OF ALKENES FROM VINYL HALIDES
    MILLON, J
    LORNE, R
    LINSTRUMELLE, G
    [J]. SYNTHESIS-STUTTGART, 1975, (07): : 434 - 435
  • [9] Coupling reaction of vinyl halides with ketones or aldehydes mediated by samarium diodide
    Kunishima, M
    Yoshimura, K
    Nakata, D
    Hioki, K
    Tani, S
    [J]. CHEMICAL & PHARMACEUTICAL BULLETIN, 1999, 47 (08) : 1196 - 1197
  • [10] SYNTHESIS OF ALPHA-HALOMETHYL KETONES - OXIDATIVE HYDROLYSIS OF VINYL HALIDES
    MORTON, HE
    LEANNA, MR
    [J]. TETRAHEDRON LETTERS, 1993, 34 (28) : 4481 - 4484