Two-dimensional phase transitions of water dipoles at mercury/aqueous solution interfaces

被引：0
|
作者：
Harinipriya, S [1 ]
Sangaranarayanan, MV [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2003年 / 42卷 / 05期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The critical temperatures pertaining to order-disorder transitions of water dipoles at mercury/aqueous solution interfaces are estimated taking into account the hydrogen bonding considerations and surface coordination effects via Gibbs free energies. The computed values are in agreement with the experimental data deduced using Laser-induced temperature jump methods as well as empirical correlations.
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页码：965 / 967
页数：3
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