Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

被引:14
|
作者
Zhou, Jianhui [1 ]
Zhang, Xiaotong [2 ]
Yan, Ying [3 ]
Hu, Jianfeng [3 ]
Wang, Hang [1 ]
Cai, Yan [3 ]
Qu, Jinqing [3 ]
机构
[1] Global Energy Interconnect Res Inst Co Ltd, State Key Lab Adv Power Transmiss Technol, Beijing 102209, Peoples R China
[2] Univ Birmingham, Sch Chem Engn, Birmingham B15 2TT, W Midlands, England
[3] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China
关键词
Capsaicin; Acrylate polymer; Solution polymerization; Antibacterial; PRESSURE-SENSITIVE ADHESIVES; BENZAMIDE DERIVATIVES; RAFT COPOLYMERIZATION; POTENTIAL APPLICATION; ACID; POLYURETHANE; WATERBORNE; COATINGS; LATEXES; RESIN;
D O I
10.1016/j.cjche.2019.03.024
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction. Capsaicin and acryloyl chloride were firstly esterified, and then applied to solution polymerization with acrylate monomers and styrene. The yield of the esterified products was about 85.3%. The polymer was characterized by Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), contact angle (CA) and antibacterial ring tests. The number-average molecular weight (M-n) of the polymer was 27214, based on the capsaicin-acrylate dosage of 6.5 wt%. The TGA revealed a stable thermal property. The contact angles of the polymers films on tinplate increased from 77.5 degrees to 86.2 degrees with the increasing amount of capsaicin-acrylate. The antibacterial tests demonstrated excellent antimicrobial capability of the polymers. (C) 2019 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co, Ltd. All rights reserved.
引用
收藏
页码:3043 / 3052
页数:10
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