On cationic mobility in Nasicon phosphates LiTi2(PO4)3 and Li0.9Ti1.9Nb0.1(PO4)3

被引：30
|
作者：
Pinus, I. Yu [1 ]
Khoroshilov, A. V. [1 ]
Gavrichev, K. S. [1 ]
Tarasov, V. P. [1 ]
Yaroslavtsev, A. B. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
SOLID STATE IONICS | 2012年 / 212卷
关键词：
Nasicon; Lithium mobility; DSC; Li-7; NMR; Phase transition; LITHIUM MOBILITY; IMPEDANCE SPECTROSCOPY; NEUTRON-DIFFRACTION; PHASE-TRANSITIONS; LI-ION; NMR; SC; NB; LI1+/-XZR2-XMX(PO4)(3); ELECTROLYTES;
D O I：
10.1016/j.ssi.2012.01.035
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A systematic examination of LiTi2(PO4)(3) and Li0.9Ti1.9Nb0.1(PO4)(3) phosphates with Nasicon structure was carried out in order to investigate "order-disorder" phase transitions. The structural features of aliovalent doped Li0.9Ti1.9Nb0.1(PO4)(3) are considered in comparison with initial LiTi2(PO4)(3). Explanations of the thermal behavior of samples are proposed based on NMR Li-7, Nb-93 data, X-ray powder diffraction. DSC and impedance spectroscopy. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：112 / 116
页数：5
相关论文
共 50 条
  • [1] THE NASICON-TYPE TITANIUM PHOSPHATES LITI2(PO4)3, NATI2(PO4)3 AS ELECTRODE MATERIALS
    DELMAS, C
    NADIRI, A
    SOUBEYROUX, JL
    SOLID STATE IONICS, 1988, 28 : 419 - 423
  • [2] LITHIUM INTERCALATION IN LITI2(PO4)3
    NADIRI, A
    DELMAS, C
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1987, 304 (09): : 415 - 418
  • [3] HYDROTHERMAL SYNTHESIS OF MTI2(PO4)3 LITI2(PO4)3, NATI2(PO4)3, KTI2(PO4)3
    YUE, Y
    PANG, WQ
    MATERIALS RESEARCH BULLETIN, 1990, 25 (07) : 841 - 844
  • [4] Structure and Vibrational Dynamics of NASICON-Type LiTi2(PO4)3
    Giarola, Marco
    Sanson, Andrea
    Tietz, Frank
    Pristat, Sylke
    Dashjay, Enkhtsetseg
    Rettenwander, Daniel
    Redhammer, Guenther J.
    Mariotto, Gino
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (07): : 3697 - 3706
  • [5] First Principles Investigation of NASICON-Structured LiTi2(PO4)3 and Mg0.5Ti2(PO4)3 Solid Electrolytes
    Fami, A. M. A.
    Wahab, N. A.
    Rani, M. S. A.
    Yaakob, M. K.
    Mustaffa, N. A.
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2022, 17 (01):
  • [6] Lithium ion conduction in LiTi2(PO4)3
    Takada, K
    Tansho, M
    Yanase, I
    Inada, T
    Kajiyama, A
    Kouguchi, M
    Kondo, S
    Watanabe, M
    SOLID STATE IONICS, 2001, 139 (3-4) : 241 - 247
  • [7] Structural and Defect Properties of LiTi2(PO4)3
    Sukumar, Raveena
    Iyngaran, Poobalasuntharam
    Kuganathan, Navaratnarajah
    BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY, 2021, 11 (05): : 13268 - 13275
  • [8] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF LITI2(PO4)3
    YUE, Y
    PANG, WQ
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1990, 9 (12) : 1392 - 1392
  • [9] La-doped LiTi2(PO4)3 ceramics
    Kazakevicius, E.
    Salkus, T.
    Dindune, A.
    Kanepe, Z.
    Ronis, J.
    Kezionis, A.
    Kazlauskiene, V.
    Miskinis, J.
    Selskiene, A.
    Selskis, A.
    SOLID STATE IONICS, 2008, 179 (1-6) : 51 - 56
  • [10] LiTi2(PO4)3 with NASICON-type structure as lithium-storage materials
    Wang, GX
    Bradhurst, DH
    Dou, SX
    Liu, HK
    JOURNAL OF POWER SOURCES, 2003, 124 (01) : 231 - 236
12345