Solid-state oxygen sensors based on phosphorescent diiodo-borondipyrromethene dye

被引：26
|
作者：
Banerjee, Swagata [1 ]
Kuznetsova, Rimma T. [2 ]
Papkovsky, Dmitri B. [1 ]
机构：
[1] Univ Coll Cork, Sch Biochem & Cell Biol, Cork, Ireland
[2] Natl Res Tomsk State Univ, Dept Phys & Colloid Chem, Tomsk 634050, Russia
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2015年 / 212卷
关键词：
Optical oxygen sensors; Solid-state phosphorescent materials; Quenched phosphorescence detection; Halogenated BODIPY dye; COMPLEXES; FLUORESCENCE;
D O I：
10.1016/j.snb.2015.02.016
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The detailed study of oxygen sensitive materials comprising diiodo-borondipyrromethene dye (I-2-BODIPY) encapsulated in hydrophobic polymers (Polysulfone, polyphenylene sulphide and fibrous polypropylene) is presented. These materials display strong absorption in the visible region and moderate room temperature phosphorescence in the near infrared region. They exhibit high sensitivity towards oxygen (tau(N2)/tau(Air) =5-5.5), high photostability, no cross-sensitivity towards humidity and quick response time in dry gas (10 s) and water (25 s). The current system can be an attractive alternative to the commonly used noble and rare metal based O-2 sensors which use e.g. metalloporphyrins or Ru(II) complexes as indicators. (C) 2015 Elsevier B.V. All rights reserved.
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页码：229 / 234
页数：6
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