Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand

被引：5

作者：

Tarique, Mohammad ^{[1
]}

机构：

[1] Prem Prakash Gupta Inst Engg, Dept Engg Chem, Bareilly 243123, Uttar Pradesh, India

来源：

E-JOURNAL OF CHEMISTRY | 2011年 / 8卷 / 04期

关键词：

Coordination complexes; Dithiocarbamates; Transition metals; TRANSITION-METAL-COMPLEXES;

D O I：

10.1155/2011/348475

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of sulphur and nitrogen containing dithiocarbamato ligand derived from diisobutylamine as well as its coordination compounds with 3d series transition metals is presented. These synthesized compounds were characterized on the basis of elemental analysis, conductometric measurements and IR spectral studies. The analytical data showed the stoichiometry 1:2 and 1:3 for the compounds of the types ML(2) {M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)} and M'L(3){M'=Cr(III) and Fe(III)} respectively. The conductometric measurements proved the non-electrolytic behaviour of all the compounds. The bidentate nature of dithiocarbamato moiety was confirmed on the basis of IR spectral data.

引用

页码：2020 / 2023

页数：4

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