Ultraviolet photodissociation dynamics of trichloroethylene at 235 nm

被引：4
|
作者：
Upadhyaya, H. P. [1 ]
Saha, A. [1 ]
Kumar, A. [1 ]
Naik, P. D. [1 ]
机构：
[1] Bhabha Atom Res Ctr, Radiat & Photochem Div, Bombay 400085, Maharashtra, India
来源：
INDIAN JOURNAL OF PHYSICS | 2012年 / 86卷 / 03期
关键词：
Photodissociation; Trichloroethylene; Resonance enhanced multiphoton ionization; REMPI; Chlorine atom; Time-of-flight mass spectrometer; TIME-OF-FLIGHT; MULTIPHOTON IONIZATION REMPI; MASS-SPECTROMETRY; MECHANISM; CHLORIDE; HCL; CL; DICHLOROETHYLENES; CHLOROETHYLENES; PHOTOFRAGMENTS;
D O I：
10.1007/s12648-012-0038-x
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The photodissociation dynamics of trichloroethylene was investigated near 235 nm, (pi,pi*) transition, by detecting the nascent products, Cl (P-2(3/2)) and Cl* (P-2(1/2)), via 2 + 1 resonance enhanced multiphoton ionization. The photofragment speed distribution, the recoil anisotropy parameter beta and the spin-orbit branching ratio for chlorine atom elimination channels were determined from time of flight profiles in polarization experiments. Based on the dynamical information, the features of potential energy surface along the reaction coordinate were discussed.
引用
收藏
页码：165 / 171
页数：7
相关论文
共 50 条
  • [1] Ultraviolet photodissociation dynamics of trichloroethylene at 235 nm
    H. P. Upadhyaya
    A. Saha
    A. Kumar
    P. D. Naik
    Indian Journal of Physics, 2012, 86 : 165 - 171
  • [2] The ultraviolet photodissociation of Cl2O at 235 nm and of HOCl at 235 and 266 nm
    Tanaka, Y
    Kawasaki, M
    Matsumi, Y
    Fujiwara, H
    Ishiwata, T
    Rogers, LJ
    Dixon, RN
    Ashfold, MNR
    JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (04): : 1315 - 1323
  • [3] Ultraviolet photodissociation of iodine monochloride (ICl) at 235, 250, and 265 nm
    Diamantopoulou, N.
    Kartakoulis, A.
    Glodic, P.
    Kitsopoulos, Theofanis N.
    Samartzis, Peter C.
    JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (19):
  • [4] Vacuum ultraviolet photodissociation dynamics of methanol at 121.6 nm
    Lucas, Michael
    Liu, Yanlin
    Bryant, Raquel
    Minor, Jasmine
    Zhang, Jingsong
    CHEMICAL PHYSICS LETTERS, 2015, 619 : 18 - 22
  • [5] Ultraviolet photodissociation dynamics of PCl3 at 235 nm: three-dimensional ion imaging and theoretical analysis
    Chichinin, A.
    Maul, C.
    Gericke, K. -H.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 23 (24) : 13583 - 13593
  • [6] The photodissociation of iodine monochloride at 235 nm
    Rogers, LJ
    Ashfold, MNR
    Matsumi, Y
    Kawasaki, M
    Whitaker, BJ
    CHEMICAL PHYSICS LETTERS, 1996, 258 (1-2) : 159 - 163
  • [7] The photodissociation of iodine monochloride at 235 nm
    Rogers, L. J.
    Ashfold, M. N. R.
    Matsumi, Y.
    Kawasaki, M.
    Chemical Physics Letters, 258 (1-2):
  • [8] PHOTODISSOCIATION OF ICI AT 235-248 NM
    TONOKURA, K
    MATSUMI, Y
    KAWASAKI, M
    KIM, HL
    YABUSHITA, S
    FUJIMURA, S
    SAITO, K
    JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05): : 3461 - 3467
  • [9] Photodissociation of ClNO2 at 235 nm
    Carter, RT
    Hallou, A
    Huber, JR
    CHEMICAL PHYSICS LETTERS, 1999, 310 (1-2) : 166 - 172
  • [10] ULTRAVIOLET PHOTODISSOCIATION DYNAMICS OF METHYL-IODIDE AT 333-NM
    FAIRBROTHER, DH
    BRIGGMAN, KA
    WEITZ, E
    STAIR, PC
    JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (05): : 3787 - 3791
12345