A tridentate ligand for preparation of bisterpyridine-like ruthenium(II) complexes with an increased excited state lifetime

被引:38
|
作者
Wolpher, H
Johansson, O
Abrahamsson, M
Kritikos, M
Sun, LC
Åkermark, B
机构
[1] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden
[2] Uppsala Univ, Dept Phys Chem, S-75123 Uppsala, Sweden
[3] Stockholm Univ, Dept Struct Chem, S-10691 Stockholm, Sweden
关键词
ruthenium modified terpyridine complex; excited state lifetime;
D O I
10.1016/j.inoche.2003.12.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new tridentate polypyridine ligand, 6-(2-picolyl)-2,2'-bipyridine, as well as its homoleptic Ru(II) complex has been prepared. Photophysical studies show a prolonged lifetime of the excited state compared to [Ru(tpy)2](2+), where tpy is 2,2':6',2"-terpyridine. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:337 / 340
页数:4
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