Design of novel seawater bittern recovery process for CO2 and SOx utilization

被引:15
|
作者
Lim, Jonghun [1 ,2 ]
Kim, Deok Ju [1 ,3 ]
Cho, Hyungtae [1 ]
Kim, Junghwan [1 ]
机构
[1] Korea Inst Ind Technol, Green Materials& Proc R&D Grp, Ulsan 44413, South Korea
[2] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 03722, South Korea
[3] Konkuk Univ, Dept Chem Engn, Seoul 05029, South Korea
关键词
Salt production; Seawater bittern; CO2 capture and utilization; SOx capture and utilization; FLUE-GAS DESULFURIZATION; FLUIDIZED-BED; CAPTURE; ABSORBENT; SORBENT; REMOVAL; MODEL; AIR;
D O I
10.1016/j.desal.2022.115995
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Considerable seawater bittern is produced during salt production. Seawater bittern can be used to reduce CO2 and SOx because of the presence of valuable mineral ions, such as K+ and Mg2+, which react with the carbonate and sulfate ions present in high concentrations. In this study, a novel seawater bittern recovery process is proposed for CO2 and SOx utilization. The proposed process has the following steps: (1) metal ion separation of the seawater bittern to produce KOH and Mg(OH)(2); (2) SOx capture and utilization using the generated Mg(OH)(2); (3) CO2 capture and utilization using the generated KOH. The pay-back period (PBP) was calculated to verify the economic feasibility of the proposed process. The results revealed an SOx and a CO2 capture efficiency of approximately 99 % and 98 %, respectively. Furthermore, the annual net revenue was approximately 153,439 USD/y based on the profit obtained from the generated product and savings on absorbent. Thus, the PBP was approximately 6.2 y.
引用
收藏
页数:12
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