Sodium Iodide/Hydrogen Peroxide-Mediated Oxidation/Lactonization for the Construction of Spirocyclic Oxindole-Lactones

被引：42
|
作者：
Li, Guofeng [2 ]
Huang, Liwu [1 ]
Xu, Jiecheng [1 ]
Sun, Wangsheng [2 ]
Xie, Junqiu [1 ]
Hong, Liang [1 ]
Wang, Rui [1 ,2 ]
机构：
[1] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510006, Guangdong, Peoples R China
[2] Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2016年 / 358卷 / 18期
关键词：
hydrogen peroxide; indolepropionic acids; oxidation; sodium iodide; spirocyclic oxindole-lactones; ENANTIOSELECTIVE SYNTHESIS; AMIDE ALLYLATION; ANNULATION; OXIDATION; CATALYSIS; INDOLES; ISATINS; IODINE; BOND; 3-BROMOOXINDOLES;
D O I：
10.1002/adsc.201600441
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The sodium iodide/hydrogen peroxide-mediated oxidation/lactonization of indolepropionic acids was achieved, affording the corresponding spirocyclic oxindole-lactones in moderate to high yields. This metal-free procedure features mild reaction conditions, non-toxicity and easy handling, with hydrogen peroxide (H2O2) as a clean oxidant.
引用
收藏
页码：2873 / 2877
页数：5
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