Synthesis, Characterization, and Application of Metal Nanoparticles Supported on Nitrogen-Doped Carbon: Catalysis beyond Electrochemistry

被引：487

作者：

He, Lin ^{[1
]}

Weniger, Florian ^{[1
]}

Neumann, Helfried ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock eV, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 41期

关键词：

heterogeneous catalysis; homogeneous catalysis; N-doped carbon; nanoparticles; single-site catalysts; FISCHER-TROPSCH SYNTHESIS; SELECTIVE OLEFIN HYDROGENATION; MOLECULARLY DEFINED COMPLEXES; COBALT-BASED NANOCATALYSTS; C COUPLING REACTIONS; AEROBIC OXIDATION; AMMONIA BORANE; FORMIC-ACID; ACTIVE-SITES; CO3O4/NGR-AT-C CATALYST;

D O I：

10.1002/anie.201603198

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal nanoparticles deposited on N-doped carbon materials have emerged as novel catalysts for various organic transformations. In this Minireview, strategies for the synthesis of metal composites on N-doped carbon supports and their state-of-the-art characterization are briefly described. The catalytic application of these fascinating materials in several industrially relevant reactions, including oxidations, hydrogenations, Fischer-Tropsch syntheses, and H-2 generation, is also summarized. Furthermore, the effects of nitrogen incorporation on the different catalytic systems are highlighted.

引用

页码：12582 / 12594

页数：13

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