Ordered mesoporous materials with pore diameters ranged from 2 nm to 50 nm possess ordered mesostruc??? tures,high surface areas,large pore volumes and tunable compositions,which have received great research interests in many fields. In the past decades,the precise synthesis,rational design,and controllable functionalization of ordered mesoporous materials have made great progresses,thereby laying a solid foundation for the practical applica??? tions,including energy storage and conversion,catalysis,biomedicine,and sensing. This review first summarizes the development history of ordered mesoporous materials comprehensively,and the milestones in this field are reviewed in detail. After that, based on the structure-property relationship, the latest progresses of ordered mesoporous materials in emerging fields,such as energy,catalysis and biomedicine are overviewed. In the last,the research challenges in this field are presented and the future perspectives are outlined.