A three-dimensional inorganic/organic hybrid material, [Ni2(4,4′-bipy)3(H2O)2V4O12]•2.5H2O

被引：9

作者：

Yang, L ^{[1
]}

Hu, CW ^{[1
]}

Naruke, H ^{[1
]}

Yamase, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷 / 07期

关键词：

D O I：

10.1107/S0108270101006229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, poly[[[diaqua(mu -4,4'-bipyridyl)dinickel(II)]-bis(mu -4,4' -bipyridyl)-di-mu -hexaoxodivanadate(2 -)] 2.5-hydrate], [Ni-2(V2O6)(2)(C10H8N2)(3)(H2O)(2)].2.5H(2)O, has been prepared hydrothermally and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The structure consists of [V2O6], [Ni(4,4' -bipy)(4)O-2] and [Ni(H2O)(2) (4,4' -bipy)(2)O-2] polyhedra, and water of crystallization. The Ni atoms and one bipyridyl group lie on centres of symmetry.

引用

页码：799 / 801

页数：3

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