The regioselective synthesis of 2-phosphinoylindoles via Rh(III)-catalyzed C-H activation

被引：22
|
作者：
Wang, Huanan [1 ]
Li, Shuaiqi [1 ]
Wang, Baiquan [1 ,2 ,3 ]
Li, Bin [1 ]
机构：
[1] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 01期
基金：
中国国家自然科学基金;
关键词：
SIMPLE INDOLE ALKALOIDS; OXIDATIVE ANNULATION; CATALYZED ANNULATION; EFFICIENT SYNTHESIS; N BOND; ALKYNES; CLEAVAGE; CYCLIZATION; VERSATILE; ALKENES;
D O I：
10.1039/c7qo00746a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The redox-neutral annulation of N-nitrosoanilines with 1-alkynylphosphine oxides under rhodium catalysis was achieved. This step-economical protocol affords 2-phosphinoylindoles in excellent regioselectivity with good functional group tolerance.
引用
收藏
页码：88 / 91
页数：4
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