High-pressure synthesis of novel lithium niobate-type oxides

被引：34
|
作者：
Inaguma, Yoshiyuki [1 ]
Yoshida, Masashi [1 ]
Tsuchiya, Takeshi [1 ]
Aimi, Akihisa [1 ]
Tanaka, Kie [1 ]
Katsumata, Tetsuhiro [1 ]
Mori, Daisuke [1 ]
机构：
[1] Gakushuin Univ, Dept Chem, Fac Sci, Toshima Ku, Tokyo 1718588, Japan
来源：
INTERNATIONAL CONFERENCE ON HIGH PRESSURE SCIENCE AND TECHNOLOGY, JOINT AIRAPT-22 AND HPCJ-50 | 2010年 / 215卷
关键词：
PHASE-TRANSITION; PEROVSKITE; ILMENITE; MNTIO3; SYSTEMATICS; SILICATES; TITANATES; MNSNO3;
D O I：
10.1088/1742-6596/215/1/012131
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
We found that two lithium niobate-type oxides, CdPbO3 and PbNiO3 were synthesized by high-pressure as metastable low-pressure perovskite-type phases. We then discussed the stability of lithium niobate-type and perovskite-type oxides relative to oxides with other structure for ABO(3) compounds. Consequently, the tolerance factor of perovskite is not the only predominant one to determine the stability and the crystal field effects of 3d transition metal ions are also important.
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页数：5
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