Vanadyl acetylacetonate as peroxide activator in osmium-catalyzed dihydroxylation of olefins by hydrogen peroxide

被引：25
|
作者：
Éll, AH [1 ]
Jonsson, SY [1 ]
Börje, A [1 ]
Adolfsson, H [1 ]
Bäckvall, JE [1 ]
机构：
[1] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 13期
关键词：
osmium-catalyzed dihydroxylation; hydrogen peroxide; vanadyl acetylacetonate;
D O I：
10.1016/S0040-4039(01)00192-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Olefins are selectively and efficiently oxidized to vicinal syn-diols by aqueous hydrogen peroxide using a coupled catalytic system consisting of osmium tetroxide, vanadyl acetylacetonate and N-methylmorpholine. (C) 2001 Published by Elsevier Science Ltd.
引用
收藏
页码：2569 / 2571
页数：3
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