Non-heme iron catalysts for epoxidation and aziridination reactions of challenging terminal alkenes: towards sustainability

被引：100
|
作者：
Fingerhut, Anja [1 ]
Serdyuk, Olga V.
Tsogoeva, Svetlana B.
机构：
[1] Univ Erlangen Nurnberg, Organ Chem Chair 1, Dept Chem & Pharm, D-91054 Erlangen, Germany
来源：
GREEN CHEMISTRY | 2015年 / 17卷 / 04期
关键词：
NONHEME IRON; ASYMMETRIC EPOXIDATION; HYDROGEN-PEROXIDE; ENANTIOSELECTIVE EPOXIDATION; AROMATIC ALKENES; RING EXPANSION; COMPLEXES; OLEFINS; OXIDATION; H2O2;
D O I：
10.1039/c4gc02413c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Through catalytic epoxidation and aziridination of olefins versatile synthetic intermediates and subunits of biologically active compounds and pharmaceuticals -epoxides and aziridines-can be obtained. The focus of this review is on recent advances in the epoxidation and aziridination of challenging terminal alkenes with respect to safety of solvents or reagents used and atom economy aspects, as well as scope and limitations of developed non-heme iron catalysts. The still large research potential for sustainable and environmentally attractive iron-based catalysts in enantioselective epoxide and aziridine synthesis is demonstrated.
引用
收藏
页码：2042 / 2058
页数：17
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