Short syntheses of enantiopure calystegine B2, B3, and B4

被引:21
|
作者
Skaanderup, PR [1 ]
Madsen, R [1 ]
机构
[1] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark
关键词
D O I
10.1039/b102353p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Calystegine B-2 B-3, and B-4 have been prepared in 5 steps from the benzyl protected methyl 6-iodoglycopyranosides of glucose, galactose and mannose, respectively, by using a zinc-mediated domino reaction followed by ring-closing olefin metathesis as the key steps.
引用
收藏
页码:1106 / 1107
页数:2
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