Effect of marine environment on the mechanical properties degradation and long-term creep failure of CFRP

The carbon fiber reinforced plastics (CFRP) has broad application prospect in the marine field, but its significate long-term performance and failure mechanism are still unclear. In this paper, the mechanical property degradation and creep failure mechanism of CFRP in marine environment were investigated by the molecular dynamics (MD) method. Based on the CFRP molecular model established in dry, pure water and salt immersion environment, the effect of service conditions on it in marine environment was explored. The results show that the marine environment can lead to a significant decrease in the mechanical properties of CFRP only in the vertical fiber direction, and the degradation extent increases with the increase of temperature. The effects of pure water immersion and salt immersion environment on its mechanical properties are basically the same. High stress level, hygrothermal environment and high temperature salt immersion environment will accelerate the creep failure of CFRP. Later, the creep failure mechanism of CFRP is analyzed from microstructure and microscopic energy. Microstructure analysis shows that water molecules could accelerate the movement of epoxy fragments and lead to CFRP failure. Microscopic energy analysis shows that the conversion process of strain energy and the decline of interface performance are the important reasons for creep failure. The finds of this paper introduce a new method to study the long-term performance of CFRP and can provide reference for the engineering application of CFRP in marine environment.