The Quantization of the E ⊗ e Jahn-Teller Hamiltonian

被引：2

作者：

Arvanitidis, Athanasios G. ^{[1
]}

Vandaele, Eva R. J. ^{[1
]}

Szopa, Marek ^{[2
]}

Ceulemans, Arnout ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, Celestijnenlaan 200F, B-3001 Leuven, Belgium

[2] Uniwersytet Slaski, Uniwersytecka 4, PL-40007 Katowice, Poland

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2017年 / 121卷 / 38期

关键词：

CANONICAL FORM;

D O I：

10.1021/acs.jpca.7b06136

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The E circle times e Jahn-Teller Hamiltonian in the Bargmann-Fock representation gives rise to a system of two coupled first-order differential equations in the complex field, which may be rewritten in the Birkhoff standard form. General leapfrog recurrence relations are derived, from which the quantized solutions of these equations can be obtained. The results are compared to the analogous quantization scheme for the Rabi Hamiltonian.

引用

页码：7246 / 7254

页数：9

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