Synthesis and structural characterisation using Rietveld and pair distribution function analysis of layered mixed titanium-zirconium phosphates

被引：9
|
作者：
Burnell, Victoria A. [1 ]
Readman, Jennifer E. [1 ]
Tang, Chiu C. [2 ]
Parker, Julia E. [2 ]
Thompson, Stephen P. [2 ]
Hriljac, Joseph A. [1 ]
机构：
[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
[2] Diamond Light Source Ltd, Didcot OX11 0DE, Oxon, England
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2010年 / 183卷 / 09期
基金：
英国工程与自然科学研究理事会;
关键词：
Layered phosphates; Titanium; Zirconium; Pair distribution function analysis; Solid solution; ION-EXCHANGE PROPERTIES; CRYSTALLINE TITANIUM; POWDER DIFFRACTION; THERMAL-BEHAVIOR; MECHANISM; SALTS; METALS;
D O I：
10.1016/j.jssc.2010.07.028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystalline metal (IV) phosphates with variable zirconium-to-titanium molar ratios of general formula (Ti1-xZrx)(HPO4)(2)center dot H2O have been prepared by precipitation of soluble salts of the metals with phosphoric acid and heating the amorphous solids in 12 M H3PO4 in an autoclave. The new materials are structurally characterised by Rietveld analysis of synchrotron X-ray powder diffraction data and pair distribution function (PDF) analysis of high energy synchrotron X-ray total scattering data. A broad range of zirconium-titanium phosphate solid solutions were formed showing isomorphous substitution of titanium by zirconium in the alpha-titanium phosphate lattice and vice versa for titanium substitution into the a-zirconium phosphate lattice. In both cases the solubility is partial with the coexistence of two substituted phases observed in samples with nominal compositions between the solubility limits. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码：2196 / 2204
页数：9
相关论文
共 19 条
  • [1] Structural characterisation of layered mixed titanium zirconium phosphates
    Readman, Jennifer E.
    Burnell, Victoria
    Hriljac, Joseph A.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2007, 63 : S54 - S54
  • [2] Structural Analysis of Molecular Materials Using the Pair Distribution Function
    Terban, Maxwell W.
    Billinge, Simon J. L.
    CHEMICAL REVIEWS, 2022, 122 (01) : 1208 - 1272
  • [3] Structural Characterization of Complex Materials using Pair Distribution Function Analysis
    Proffen, Thomas
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2010, 66 : S72 - S72
  • [4] Structural analysis of complex materials using the atomic pair distribution function - a practical guide
    Proffen, T
    Billinge, SJL
    Egami, T
    Louca, D
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2003, 218 (02): : 132 - 143
  • [5] Structural Analysis of Al, Ni, and Cu Using the Maximum Entropy Method, Multipole and Pair Distribution Function
    Robert, Muthaian Charles
    Saravanan, Ramachandran
    Saravanakumar, Krishnamoorthy
    Rani, Murugesan Prema
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2009, 64 (5-6): : 361 - 369
  • [6] Local structural studies of Ba1-xKxFe2As2 using atomic pair distribution function analysis
    Joseph, B.
    Zinth, V.
    Brunelli, M.
    Maroni, B.
    Johrendt, D.
    Malavasi, L.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2011, 23 (11)
  • [7] Quantitative Structural Analysis of AuAg Nanoparticles Using a Pair Distribution Function Based on Precession Electron Diffraction: Implications for Catalysis
    Correa, Leonardo M.
    Moreira, Murilo
    Rodrigues, Varlei
    Ugarte, Daniel
    ACS APPLIED NANO MATERIALS, 2021, 4 (11) : 12541 - 12551
  • [8] Structural study of biotic and abiotic poorly-crystalline manganese oxides using atomic pair distribution function analysis
    Zhu, Mengqiang
    Farrow, Christopher L.
    Post, Jeffrey E.
    Livi, Kenneth J. T.
    Billinge, Simon J. L.
    Ginder-Vogel, Matthew
    Sparks, Donald L.
    GEOCHIMICA ET COSMOCHIMICA ACTA, 2012, 81 : 39 - 55
  • [9] Observation of Liquid Phase Synthesis of Sulfide Solid Electrolytes Using Time-Resolved Pair Distribution Function Analysis
    Ohara, Koji
    Masuda, Naoya
    Yamaguchi, Hiroshi
    Yao, Atsushi
    Tominaka, Satoshi
    Yamada, Hiroki
    Hiroi, Satoshi
    Takahashi, Masakuni
    Yamamoto, Kentaro
    Wakihara, Toru
    Uchimoto, Yoshiharu
    Utsuno, Futoshi
    Kimura, Shigeru
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2020, 257 (11):
  • [10] Local Structural Evolution of Mechanically Alloyed Mg50Co50 Using Atomic Pair Distribution Function Analysis
    Kim, Hyunjeong
    Nakamura, Jin
    Shao, Huaiyu
    Nakamura, Yumiko
    Akiba, Etsuo
    Chapman, Karena W.
    Chupas, Peter J.
    Proffen, Thomas
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (15): : 7723 - 7728
12