A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

被引：44
|
作者：
Cooper, Oliver J. [1 ]
Wooles, Ashley J. [1 ]
McMaster, Jonathan [1 ]
Lewis, William [1 ]
Blake, Alexander J. [1 ]
Liddle, Stephen T. [1 ]
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期
基金：
英国工程与自然科学研究理事会;
关键词：
lithium; methandiide; N; P ligands; planar four-coordinate carbon; structure elucidation; TETRACOORDINATE CARBON; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; CHEMISTRY; HEXAPHENYLCARBODIPHOSPHORANE; TRIBOLUMINESCENCE; POLYMORPHS; COMPLEXES; RADII;
D O I：
10.1002/anie.201002483
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It's plain to see: A monomeric dilithio methandiide features a distorted transplanar four-coordinate carbon atom. The nature of this compound as established by an X-ray diffraction study (see picture: C black, N blue, P magenta, Li red) and supported by calculations. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5570 / 5573
页数：4
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