Steady-state luminescence of polymers

被引:2
|
作者
Reigada, R
Sokolov, IM
机构
[1] Humboldt Univ, Inst Phys, D-12489 Berlin, Germany
[2] Univ Barcelona, Fac Quim, E-08028 Barcelona, Spain
关键词
D O I
10.1021/ma048593b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We consider a simple model for steady-state luminescence of single polymer chains in a dilute solution in the case when excitation quenching is due to energy transfer between a donor and an acceptor attached to the ends of the chain. We present numerical results for Rouse chains without or with hydrodynamic interactions, which are taken into account in a perturbative manner. We consider the situations of a quiescent solvent as well as the chain in a shear flow and discuss the dependence of the steady-state luminescence intensity on the strength of hydrodynamic interaction and on the shear rate in the flow.
引用
收藏
页码:3504 / 3510
页数:7
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