The X-ray crystallographic structures, spectral and magnetic properties of nickel(II), copper(II) and cobalt(II) complexes with tetra(3-iso-propylpyrazol-1-yl)borate

被引：12
|
作者：
Kisala, J
Ciunik, Z
Drabent, K
Ruman, T
Wolowiec, S
机构：
[1] Wroclaw B Beirut Univ, Fac Chem, PL-50383 Wroclaw, Poland
[2] Rzeszow Univ Technol, Fac Chem, PL-35959 Rzeszow, Poland
来源：
POLYHEDRON | 2003年 / 22卷 / 13期
关键词：
cobalt; nickel; copper; tetra(3-iso-propylpyrazolyl)borate; structures; magnetism;
D O I：
10.1016/S0277-5387(03)00331-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tetra(3-iso-propylpyrazol-1-yl)borate ligand (L) forms mono-ligand LMX and bis-ligand L2M complexes (where M = Ni(11), and Cu(II), and X = Cl- or NO3-) depending on the stoichiometry of the synthesis, while a polynuclear (NCS)(2)Co(L)Co(L)Co(NCS)(2) complex is obtained when excess of cobalt(11) thiocyanate is used. The L coordinates to metal ions in a kappa(3) fashion in LNiCl, LNi(NO3)(5-(i)PrpzH) and LCuCl(5-(i)PrpzH), whereas a kappa(2) binding mode was found in L2Ni and in unique (NCS)(2)Co(L)Co(L)Co(NCS)(2), in which L bridges two metal ions. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1645 / 1652
页数：8
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