The synergistic effect of cobalt on a Pd/Co catalyzed Suzuki-Miyaura cross-coupling in water

被引:27
|
作者
You, Li-Xin [1 ]
Liu, Hui-Jie [1 ]
Cui, Lan-Xin [1 ]
Ding, Fu [1 ]
Xiong, Gang [1 ]
Wang, Shu-Ju [1 ]
Ren, Bao-Yi [1 ]
Dragutan, Ileana [2 ]
Dragutan, Valerian [2 ]
Sun, Ya-Guang [1 ]
机构
[1] Shenyang Univ Chem Technol, Key Lab Inorgan Mol Based Chem Liaoning Prov, Shenyang 110142, Peoples R China
[2] Romanian Acad Bucharest, Inst Organ Chem, Bucharest 060023, Romania
关键词
LANTHANIDE COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; HIGHLY EFFICIENT; PALLADIUM; ACID; LIGAND; COMPLEXES; KETONES; SALTS; HECK;
D O I
10.1039/c6dt03628g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This work introduces the new trimetallic complex CoPd2(HBPDC) 2Cl(4)center dot(H2O)(4)(H2BPDC = 2,2'-bipyridine-4,4'-dicarboxylic acid) as a highly efficient and more cost-effective catalyst for a Suzuki-Miyaura reaction proceeding in water, without additives and under aerobic conditions. Catalytic studies revealed a synergistic Co-Pd cooperativity, fostered by ligation through H2BPDC, and accounting for the superior performance of the hetero-bimetallic complex vs. its Co-free counterpart.
引用
收藏
页码:18455 / 18458
页数:4
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