Mechanochemical reaction of 1,10-phenanthroline with metallic iron

被引：0
|
作者：
Drozdova, MK [1 ]
Myakishev, KG [1 ]
Ikorskii, VN [1 ]
Aksenov, VK [1 ]
Volkov, VV [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 04期
关键词：
Iron; Physical Chemistry; 3H2O; Absorption Spectrum; Carbonyl;
D O I：
10.1023/A:1023352421497
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Fe(II) complex is isolated from the products of mechanical activation of a mixture of the powdered carbonyl Fe and 1,10-phenanthroline. According to the data of elemental analysis, an electronic absorption spectra, magnetochemical and EPR studies, the isolated compound is [FePhen(3)](2+) Phen(-)OH(-) . 3H(2)O that contains tains Phen(-) radical-anion.
引用
收藏
页码：234 / 236
页数：3
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