Synthesis, characterization and DFT studies of 1, 1′-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes

被引：14
|
作者：
Kaur-Ghumaan, Sandeep [1 ]
Sreenithya, A. [2 ]
Sunoj, Raghavan B. [2 ]
机构：
[1] Univ Delhi, Dept Chem, Delhi 110007, India
[2] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
来源：
JOURNAL OF CHEMICAL SCIENCES | 2015年 / 127卷 / 03期
关键词：
Bioinorganic chemistry; hydrogenase enzyme; bidentate phosphine; proton reduction; redox active ligands; density functional calculations; ELECTROCHEMICAL PROTON REDUCTION; EFFECTIVE CORE POTENTIALS; IRON-SULFUR COMPLEXES; ACTIVE-SITE; ONLY HYDROGENASE; STRUCTURAL-CHARACTERIZATION; CLOSTRIDIUM-PASTEURIANUM; MOLECULAR CALCULATIONS; COORDINATION; BRIDGE;
D O I：
10.1007/s12039-015-0809-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of [Fe-2(CO)(6)(mu-toluene-3, 4-benzenedithiolate)] 1 and bidentate diphosphine, 1, 1'-bis(diphenylphosphino)ferrocene (dppf) has been studied. New complexes obtained have been characterized by various spectroscopic techniques as bioinspired models of the iron hydrogenase active site. The crystal structure of [Fe-2(CO)(5)(kappa(1)-dppfO)(mu-toluene-3, 4-benzenedithiolate)] 4 is reported.
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页码：557 / 563
页数：7
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