An efficient Sm and Ge co-doped ceria nanocomposite electrolyte for low temperature solid oxide fuel cells

被引:37
|
作者
Arshad, Muhammad Sarfraz [1 ]
Raza, Rizwan [2 ]
Ahmad, M. Ashfaq [2 ]
Abbas, Ghazanfar [2 ]
Ali, Amjad [2 ]
Rafique, Asia [2 ]
Ullah, M. Kaleem [2 ]
Rauf, Sajid [2 ]
Asghar, M. Imran [3 ]
Mushtaq, Naveed [2 ]
Atiq, Shahid [1 ]
Naseem, Shahzad [1 ]
机构
[1] Univ Punjab, Ctr Excellence Solid State Phys, Quaid E Azam Campus, Lahore 54590, Pakistan
[2] COMSATS Inst Informat Technol, Dept Phys, Lahore 54000, Pakistan
[3] Aalto Univ, Dept Appl Phys, F-10007 Aalto, Finland
关键词
Electrolyte; Solid oxide fuel cells; Germanium; Nanocomposite; Morphology; IT-SOFCS; MICROSTRUCTURE; PERFORMANCE; STABILITY; CATHODE;
D O I
10.1016/j.ceramint.2017.09.155
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study we present a new nanocomposite electrolyte based on samarium (Sm) and germanium (Ge) co doped ceria Ce0.7Sm0.15Ge0.15O2.delta (SGeDC). The nanocomposite electrolyte was prepared using co-precipitation method. The crystal structure and surface morphology were determined using x-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Four probe dc conductivity indicated the value of 0.074 S/cm at 650 degrees C. The Fuel cell performance was carried out using hydrogen as fuel. The maximum OCV observed was 0.95 V while the peak power density came out to be 600 mW/cm(2) at 600 degrees C. It is suggested that adding Ge, the conductivity as well as performance of this new nanocomposite electrolyte is comparatively enhanced and it can find potential applications in low temperature solid oxide Fuel cells (LTSOFCs).
引用
收藏
页码:170 / 174
页数:5
相关论文
共 50 条
  • [1] Lowering the Sintering Temperature of Low-Temperature Solid Oxide Fuel Cells with Sm3+ And Nd3+ Co-Doped Ceria Electrolyte
    Luo, Xiaoyan
    Wang, Cancan
    Yang, Yang
    Chen, Yonghong
    Huang, Qi
    Lin, Bin
    [J]. PROCEEDINGS OF 2017 2ND INTERNATIONAL CONFERENCE ON POWER AND RENEWABLE ENERGY (ICPRE), 2017, : 1082 - 1088
  • [2] Study on Gd and Mg co-doped ceria electrolyte for intermediate temperature solid oxide fuel cells
    Wang, FY
    Chen, SY
    Qin, W
    Yu, SX
    Cheng, SF
    [J]. CATALYSIS TODAY, 2004, 97 (2-3) : 189 - 194
  • [3] Synthesis and characterization of co-doped ceria-based electrolyte material for low temperature solid oxide fuel cell
    Altaf, Faizah
    Batool, Rida
    Gill, Rohama
    Abbas, Ghazanfar
    Raza, Rizwan
    Khan, M. Ajmal
    Rehman, Zohaib-ur
    Ahmad, Muhammad Ashfaq
    [J]. CERAMICS INTERNATIONAL, 2019, 45 (08) : 10330 - 10333
  • [4] Ceria co-doped with calcium (Ca) and strontium (Sr): a potential candidate as a solid electrolyte for intermediate temperature solid oxide fuel cells
    Jaiswal, Nandini
    Kumar, Devendra
    Upadhyay, Shail
    Parkash, Om
    [J]. IONICS, 2014, 20 (01) : 45 - 54
  • [5] Ceria co-doped with calcium (Ca) and strontium (Sr): a potential candidate as a solid electrolyte for intermediate temperature solid oxide fuel cells
    Nandini Jaiswal
    Devendra Kumar
    Shail Upadhyay
    Om Parkash
    [J]. Ionics, 2014, 20 : 45 - 54
  • [6] Electrical properties of praseodymium and samarium co-doped ceria electrolyte for low-temperature solid oxide fuel cell application
    Eressa, Lemessa Asefa
    Rao, P. V. Bhaskara
    [J]. BULLETIN OF MATERIALS SCIENCE, 2021, 44 (04)
  • [7] Electrical properties of praseodymium and samarium co-doped ceria electrolyte for low-temperature solid oxide fuel cell application
    Lemessa Asefa Eressa
    P V Bhaskara Rao
    [J]. Bulletin of Materials Science, 2021, 44
  • [8] 3D printed Sm-doped ceria composite electrolyte membrane for low temperature solid oxide fuel cells
    Feng, Zuying
    Liu, Liang
    Li, Lingyao
    Chen, Jiahe
    Liu, Yuhong
    Li, Yan
    Hao, Liang
    Wu, Yan
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (26) : 13843 - 13851
  • [9] Doped ceria anode interlayer for low-temperature solid oxide fuel cells with nanothin electrolyte
    Ji, Sanghoon
    Lee, Yoon Ho
    Park, Taehyun
    Cho, Gu Young
    Noh, Seungtak
    Lee, Yeageun
    Kim, Minwoo
    Ha, Seungbum
    An, Jihwan
    Cha, Suk Won
    [J]. THIN SOLID FILMS, 2015, 591 : 250 - 254
  • [10] Low-temperature ceria-electrolyte solid oxide fuel cells for efficient methanol oxidation
    Meng, Xie
    Zhan, Zhongliang
    Liu, Xuejiao
    Wu, Hao
    Wang, Shaorong
    Wen, Tinglian
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (23) : 9961 - 9964