Design and construction of lanthanide metal-organic frameworks through mixed-ligand strategy: Sensing property of acetone and Cu2+

被引:16
|
作者
Sun, Zan
Li, Hongdao
Sun, Guifang
Guo, Jianni
Ma, Yue
Li, Licun [1 ]
机构
[1] Nankai Univ, Coll Chem, Dept Chem, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
Lanthanide metal-organic frameworks; Dual-functional luminescent sensor; High sensitivity and selectivity; Acetone; Cu2+; LUMINESCENCE PROPERTIES; COORDINATION POLYMERS; TOPOLOGICAL ANALYSIS; MAGNETIC-PROPERTIES; FLUORESCENT SENSOR; AQUEOUS-SOLUTION; BUILDING UNITS; FE3+ IONS; MOFS; SITES;
D O I
10.1016/j.ica.2017.08.053
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Four isostructural 3D lanthanide metal-organic frameworks (Ln-MOFs) {[Ln(L)(ox)(0.5)(H2O)(2)]center dot H2O}(n) (Ln = Pr 1, Nd 2, Sm 3 and Eu 4) were constructed by 5-hydroxyisophthalic acid (H2L) and oxalate (ox) through solvothermal methods, which show a (4,5)-connected tcs net with the point symbol of (4(4).6(2)) (4(4).6(6)). Compound 4 exhibits an intense red fluorescence in solid state and is an excellent dual-functional recyclable luminescent sensor which can sense acetone and Cu2+ with high sensitivity and selectivity simultaneously. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:51 / 56
页数:6
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