Promising activated carbon derived from sugarcane tip as electrode material for high-performance supercapacitors

被引:21
|
作者
Wei, Bo [1 ]
Wei, Tiantian [1 ]
Xie, Caifeng [1 ,2 ,3 ]
Li, Kai [1 ,2 ,3 ]
Hang, Fangxue [1 ,2 ,3 ]
机构
[1] Guangxi Univ, Sch Light Ind & Food Engn, Nanning 530004, Peoples R China
[2] Prov & Ministerial Collaborat Innovat Ctr Ind, Nanning 530004, Peoples R China
[3] Minist Educ, Engn Res Ctr Sugar Ind & Comprehens Utilizat, Nanning 530004, Peoples R China
关键词
HIERARCHICAL POROUS CARBON; NANOPOROUS CARBON; WASTE; ENERGY; SHELLS; HYDROXIDE; DOTS; PEEL; AREA;
D O I
10.1039/d1ra04143f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We present a simple, low-cost method for producing activated-carbon materials from sugarcane tips (ST) via two-step pre-carbonization and KOH activation treatment. After optimizing the amount of KOH, the resulting ST-derived activated carbon prepared with a KOH to PC-ST mass ratio of 2 (ACST-2) contained 17.04 wt% oxygen and had a large surface area of 1206.85 m(2) g(-1), which could be attributed to the large number of micropores in ACST-2. In a three-electrode system, the ACST-2 electrode exhibited a high specific capacitance of 259 F g(-1) at 0.5 A g(-1) and good rate capability with 82.66% retention from 0.5 to 10 A g(-1). In addition, it displayed a high capacitance retention of 89.6% after 5000 cycles at a current density of 3 A g(-1), demonstrating excellent cycling stability. Furthermore, the ACST-2//ACST-2 symmetric supercapacitor could realize a high specific energy density of 7.93 W h kg(-1) at a specific power density of 100 W kg(-1) in 6 M KOH electrolyte. These results demonstrate that sugarcane tips, which are inexpensive and easily accessible agricultural waste, can be used to create a novel biomass precursor for the production of low-cost activated carbon materials for high-performance supercapacitors.
引用
收藏
页码:28138 / 28147
页数:10
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