Magnetocaloric effect in ErNi2 melt-spun ribbons

被引:13
|
作者
Sanchez Llamazares, J. L. [1 ]
Ibarra-Gaytan, P. [1 ,2 ]
Sanchez-Valdes, C. F. [3 ]
Rios-Jara, D. [1 ]
Alvarez-Alonso, P. [4 ]
机构
[1] Inst Potosino Invest Cient & Tecnolog AC, Camino Presa San Jose 2055,Col Lomas 4a, San Luis Potosi 78216, San Luis Potosi, Mexico
[2] Univ Pavol Jozef Safarik, CPM TIP, Pk Angelinum 9, Kosice 04154, Slovakia
[3] Univ Autonoma Ciudad Juarez UACJ, Div Multidisciplinaria, Ciudad Univ, Ciudad Juarez 32579, Chihuahua, Mexico
[4] Univ Oviedo, Dept Fis, Calvo Sotelo S-N, Oviedo 33007, Spain
关键词
ErNi2 Laves phase; Melt-spun ribbons; Magnetic entropy change; Adiabatic temperature change; Rare Earths; INTERMETALLIC COMPOUNDS; MAGNETIC REFRIGERATION; RARE-EARTH; CAPACITY;
D O I
10.1016/j.jre.2019.07.011
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
ErNi2 ribbons were produced by rapid solidification using the melt spinning technique. Their structural, magnetic and magnetocaloric properties in the as-solidified state were studied by X-ray diffraction, scanning electron microscopy, magnetization and specific heat measurements. Samples are single phase with the MgCu2-type crystal structure, a Curie temperature T-C of 6.8 K and a saturation magnetization at 2 K and 5 T of 124.0 A. m(2)/kg. For a magnetic field change mu(0)Delta H of 5 T (2 T) ribbons show a maximum magnetic entropy change vertical bar Delta S-M(peak)vertical bar of 24.1 (16.9) J/(kg . K), and an adiabatic temperature change Delta T-ad(max) of 8.1 (4.4) K; this is similar to the previously reported literature for bulk alloys that were processed through conventional melting techniques followed by prolonged thermal annealing. In addition, the samples also show slightly wider Delta S-M(T) curves with respect to bulk alloys leading to a larger refrigerant capacity. (C) 2020 Chinese Society of Rare Earths. Published by Elsevier B.V.
引用
收藏
页码:612 / 616
页数:5
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