Heterogeneous catalysts for hydroamination reactions:: structure-activity relationship

被引：78

作者：

Penzien, JC

Haessner, C

Jentys, A

Köhler, K

Müller, TE

Lercher, JA

机构：

[1] Tech Univ Munich, Lehrstuhl Tech Chem 2, D-85747 Garching, Germany

[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

JOURNAL OF CATALYSIS | 2004年 / 221卷 / 02期

关键词：

hydroamination; addition; amines; zeolite BEA; ion exchange; copper; zinc; X-ray absorption; EPR; catalysis;

D O I：

10.1016/S0021-9517(03)00283-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic activity of ion-exchanged zeolite BEA for hydroamination reactions, such as the cyclization of 6-aminohex-1-yne and 3-aminopropylvinyl ether and the intermolecular addition of aniline to phenylacetylene, was studied. The most active catalysts were Cu(I)/HBEA, Rh(I)/H-BEA, and Zn/H-BEA. These catalysts were fully characterized and the oxidation state and the local environment of copper, in particular, were explored with XANES and EPR spectroscopy. For Zn/H-BEA zeolites the catalytic activity of the material was related to the local structure around the zinc cations. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：302 / 312

页数：11

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