Spectrophotometric determination of the formation constants of some transition metal cations with a new synthetic Schiff base in dichloromethane and chloroform using rank annihilation factor analysis

The complex formation between a new synthesized Schiff base and the cations Ni2+, Co2+, Cu2+, Zn2+ in dichloromethane (DCM) and chloroform solutions was investigated spectrophotometrically using rank annihilation factor analysis (RAFA). The results of mole ratio plots and continuous variation data show the stoichiometry of complexation were found to be 1:1, and 2:1 metal ion to ligand. The stoichiometry was obtained as 1:1 metal ion to ligand ratio for Co2+, Ni2+ and Zn2+ in chloroform and 2:1 for Cu2+. In DCM the stoichiometry was obtained as 1:1 for Co2+ and 2:1 for Ni2+ and Zn2+ and a consecutive 2:1 metal ion to ligand ratio was obtained for Cu2+. Formation constants of these complexes were estimated by application of RAFA on spectrophotometric data. In this process the contribution of ligand was removed from the absorbance data matrix when the complex stability constant acts as an optimizing object and simply combined with the pure spectrum of the ligand, the rank of the original data matrix can be reduced by one by annihilating the information of the ligand from the original data matrix. (C) 2010 Elsevier B.V. All rights reserved.