Froth heights on dual-flow trays with a heterogeneous binary azeotropic system and a heterogeneous ternary system with a homogeneous azeotrope

被引:7
|
作者
Furzer, IA [1 ]
机构
[1] Univ Sydney, Dept Chem Engn, Sydney, NSW 2006, Australia
关键词
Azeotropes - Density of gases - Ethanol - Ternary systems;
D O I
10.1021/ie000874u
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Visual froth height measurements and the clear liquid heights on 20% free area dual-flow trays, operated at total reflux, have been obtained on the homogeneous system of water-steam, on the heterogeneous systems of ethyl acetate-water and ethyl acetate-ethanol-water, and in the homogeneous region near the homogeneous ternary azeotrope of that ternary system. The experimental results were obtained under distilling conditions at a total pressure of 101.3 kPa for a range of liquid and vapor densities and vapor velocities. The churn flow conditions on the dual-flow trays at total reflux were found to have the characteristic of constant volume fraction liquid in the froth for all systems investigated: Phi (L) = 0.291; h(f) < 0.300. A correlating equation for the froth height that contains the impact pressure was found for all systems investigated to be h(f) = 2.625(1/2 rho (V)u(2))rootp(V)/rho (L) with h(f) < 0.300. A dimensionless correlating form, based on a modified Froude number, was found to be suitable for all systems: Fr-M = 280.0 x 10(-6)(rho (V)/rho (L))(-1/2) with hf < 0.300. The clear liquid height was found for all systems to follow h(CL) = Phi (L)h(f) with h(f) < 0.300. The dimensionless correlation for froth heights for all systems could be converted to a flooding vapor velocity relationship at total reflux for dual-flow trays by u(fl) = 0.0283 rootZ(rho (V)/rho (L))(-3/4) with Z < 0.300.
引用
收藏
页码:4951 / 4966
页数:16
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