Eco-friendly and sustainable synthetic approaches to biologically significant fused N-heterocycles

被引：25

作者：

Gupta, Shiv Shankar ^{[1
,2
]}

Kumari, Surekha ^{[1
,2
]}

Kumar, Inder ^{[1
,2
]}

Sharma, Upendra ^{[1
,2
]}

机构：

[1] CSIR Inst Himalayan Bioresource Technol, Nat Prod Chem & Proc Dev Div, Palampur 176061, Himachal Prades, India

[2] CSIR Inst Himalayan Bioresource Technol, AcSIR, Palampur 176061, Himachal Prades, India

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2020年 / 56卷 / 04期

关键词：

drug molecules; fused heterocycles; metal-free approach; multicomponent reactions; CATALYST-FREE; DERIVATIVES; CHEMISTRY;

D O I：

10.1007/s10593-020-02678-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review summarizes environmentally benign approaches for the synthesis of fused N-heterocycles since 2011. It is mainly focused on one-pot, multicomponent protocols for generating fused N-heterocyclic moieties with biological significance in atom-efficient manner. Several attractive and cost-effective approaches such as metal-, catalyst-, and solvent-free methods are discussed in this review. Electrochemical concept as green and environmentally optional strategy to produce fused N-heterocycles is also discussed. Synthesis of natural bioactive compounds like clausine V, glycoborine, and popular commercial drug alprazolam (Xanax) by utilizing such strategy is described.

引用

页码：433 / 444

页数：12

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