Octanuclear Cu(I)-dithiophosphates: An Efficient Catalyst System for N-Arylation of Azoles, Amines, and Amides

被引：4

作者：

Wu, Cheng-Chieh ^{[1
]}

Lee, Bo-Han ^{[1
]}

Liao, Ping-Kuei ^{[1
]}

Fang, Ching-Shiang ^{[1
]}

Liu, C. W. ^{[1
]}

机构：

[1] Natl Dong Hwa Univ, Dept Chem, Hualien 97401, Taiwan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2012年 / 59卷 / 04期

关键词：

Copper; S-donor ligands; N-arylation; Cross-coupling; COUPLING REACTIONS; ARYL HALIDES; COPPER CATALYST; CLUSTERS; ULLMANN; PRECATALYSTS; AMIDATION; PRODUCTS; CU-8(I);

D O I：

10.1002/jccs.201100592

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of a C-N bond via the cross-couplings of aryl iodides with azoles, aryl amine, and amides can be successfully achieved in decent yield by the utilization of both [Cu-8(H){S2P((OPr)-Pr-i)(2)}(6)](+) and [Cu-8{S2P(OEt)(2)}(6)](2+) as the pre-catalysts.

引用

页码：480 / 484

页数：5

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