Pushing the Limits for Thiol-Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day

被引：152

作者：

Antoni, Per ^{[1
,2
,3
]}

Robb, Maxwell J. ^{[2
,3
]}

Campos, Luis ^{[2
,3
]}

Montanez, Maria ^{[1
]}

Hult, Anders ^{[1
]}

Malmstrom, Eva ^{[1
]}

Malkoch, Michael ^{[1
]}

Hawker, Craig J. ^{[2
,3
]}

机构：

[1] Royal Inst Technol, Sch Chem & Chem Sci, Div Coating Technol, S-10044 Stockholm, Sweden

[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Dept Mat, Santa Barbara, CA 93106 USA

[3] Univ Calif Santa Barbara, MRL, Santa Barbara, CA 93106 USA

来源：

MACROMOLECULES | 2010年 / 43卷 / 16期

基金：

瑞典研究理事会;

关键词：

BROMO CLICK CHEMISTRY; RAPID SYNTHESIS; 1,3-DIPOLAR CYCLOADDITIONS; BIFUNCTIONAL DENDRIMERS; RADICAL POLYMERIZATION; MATERIALS SCIENCE; TERMINAL ALKYNES; STAR POLYMERS; MACROMOLECULES; COPOLYMERS;

D O I：

10.1021/ma101242u

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dendrimer synthesis should not be tedious and time-consuming. By utilizing an AB(2)-CD2 approach and having orthogonal, "clickable" groups on each monomer, the time for dendrimer assembly can be drastically reduced. This was shown by preparation of a sixth generation dendrimer from starting monomer units in a single day.

引用

页码：6625 / 6631

页数：7