Shannon's Measure of Information and the Thermodynamic Entropy

被引:0
|
作者
Ben-Naim, Arieh [1 ]
机构
[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel
关键词
Entropy; Thermodynamics; Shannon's measure of information;
D O I
10.1063/1.3703629
中图分类号
O59 [应用物理学];
学科分类号
摘要
This lecture is concerned with two topics: First, we discuss the widespread confusion between a descriptor of the state of the system, and changes in the states in a spontaneous process, on one hand, and a descriptor of entropy on the other hand. The second, is concerned with a clear distinction between Shannon's Measure of Information (SMI), and the Thermodynamic Entropy. The first is defined on any distribution, and therefore it is a very general concept. On the other hand Entropy is defined on a very special set of distributions. Therefore it is suggested that this conference will be called MaxSMI rather than MaxEnt. Next we show that the Shannon measure of Information (SMI) provides a solid and quantitative basis for the interpretation of the thermodynamic entropy. For an ideal gas the entropy measures the uncertainty in the location and momentum of a particle, as well as two corrections due to the uncertainty principle and the indistinguishability of the particles.
引用
收藏
页码:129 / 142
页数:14
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