Dressed potential energy surface of the hydrogen molecule in high-frequency Floquet theory

被引：0
|
作者：
Del Valle, CP
Lefebvre, R
Atabek, O
机构：
[1] Photophys Mol Lab, F-91405 Orsay, France
[2] Univ Paris 06, UFR Phys Fondamentale & Appl, F-75230 Paris, France
来源：
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY | 1998年 / 70卷 / 01期
关键词：
alignment; intense fields; dressed molecular states; Floquet theory; hydrogen molecule;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The potential energy surface resulting from the application of the high-frequency Floquet theory to the hydrogen molecule coupled to a linearly polarized field is determined. The method uses a standard quantum chemistry program. It is found that the anisotropy of the surface is more pronounced than in the case of the hydrogen molecular cation. This is indicative of a strong propensity for an alignment of the internuclear axis in the direction of the applied field. (C) 1998 John Wiley & Sons, Inc.
引用
收藏
页码：199 / 203
页数：5
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