Synthesis and molecular structure of (Mes2C6H3)B(Br)N(H)[(i-Pr2C6H3)] and an ab initio examination of CH3BBr2 and CH3B(Br)NH2

被引：3

作者：

Li, XW

Xie, YM

Su, JR

Schaefer, HF

Robinson, GH ^{[1
]}

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

[2] Univ Georgia, Ctr Computat Quantum Chem, Athens, GA 30602 USA

来源：

MAIN GROUP CHEMISTRY | 1998年 / 2卷 / 04期

关键词：

D O I：

10.1080/10241229812331341529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of (2, 6-dimesitylphenyl)boron dibromide, (MeS2C6H3)BBr2 I, With [2,6-di-i-propylphenyl)amino]lithium, [(i-Pr2C6H3)N(H)Li, affords 2, 6-dimesitylphenyl[(2,6-di-ipropylphenyl)amino]boron bromide, (Mes(2)C(6)H(3))B(Br)N(H)[(i-Pr2C6H3)], II. II has been characterized by elemental analyses,H-1 and C-13 NMR, and single crystal X-ray diffraction. nb initia examination of model molecules CH3BBr2, III, and CH3B(Br)NH2, IV, supports a measure of pi-bonding in the B-Br and B-N bonds in III and IV.

引用

页码：323 / 327

页数：5

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