PhCH=P(MeNCH2CH2)3N:: A novel ylide in the Wittig reaction

被引：18
|
作者：
Wang, Z [1 ]
Verkade, JG [1 ]
机构：
[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 51期
关键词：
D O I：
10.1016/S0040-4039(98)02157-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The title semi-stabilized ylide prepared from the commercially available non-ionic superbase P(MeNCH2CH2)(3)N reacts with aldehydes to give alkenes in high yield with surprisingly quantitative E selectivity. (C) 1998 Elsevier Science Ltd. Ail rights reserved.
引用
收藏
页码：9331 / 9334
页数：4
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