Chiral platinum(II) complexes.: Crystal and molecular structures of cis-[PtPhCl((R,R)-CHIRAPHOS)] and cis-[PtCl2((R,R)-CHIRAPHOS)]

被引：10
|
作者：
Johansson, MH [1 ]
Malmström, T [1 ]
Wendt, OF [1 ]
机构：
[1] Univ Lund, Dept Chem, S-22100 Lund, Sweden
来源：
INORGANICA CHIMICA ACTA | 2001年 / 316卷 / 1-2期
关键词：
crystal structures; platinum complexes; chiral phosphine complexes;
D O I：
10.1016/S0020-1693(01)00396-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction between trans-PtPhCl(SMe2)(2) and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P2(1) with a = 12.875(3), b = 18.012(4), c = 13.864(3) Angstrom, beta = 109.71(3)degrees and Z = 4. In CDCl3 1 reacts with Ph2P(C6H4)CH2N(Me)(COEt) to give cis [PtCl2((R,R)-CHIRAPHOS)] (2), the crystals of which are monoclinic, space group P2(1) with a = 7.8052(16), b = 17.679(4), c = 9.843(2) Angstrom, beta = 100.67(3)degrees and Z = 2. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码：149 / 152
页数：4
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