Relationship between rate and distance

被引：40
|
作者：
Menger, FM
Galloway, AL
Musaev, DG
机构：
[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA
[2] Emory Univ, Cherry L Emerson Ctr Sci Computat, Atlanta, GA 30322 USA
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 18期
关键词：
D O I：
10.1039/b306342a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The activation energies for four Smiles reactions vary with the distance squared between the nucleophilic and electrophilic atoms (consistent with theoretical considerations and pertinent to organic and enzymatic catalyses).
引用
收藏
页码：2370 / 2371
页数：2
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