Cure kinetics characterization of soy-based epoxy resins for infusion moulding process

被引:3
|
作者
Subbiah, Rajkumar [1 ,2 ]
Tjong, Jimi [1 ,3 ]
Nayak, Sanjay K. [2 ]
Sain, Mohini [1 ,4 ]
机构
[1] Univ Toronto, Fac Forestry Chem Engn, 33 Willcocks St, Toronto, ON M5S 3B3, Canada
[2] CIPET, Adv Res Sch Technol & Prod Simulat, Madras 600032, Tamil Nadu, India
[3] Ford Motor Co, Powertrain Engn Res & Dev Ctr, Windsor, ON, Canada
[4] King Abdulaziz Univ, Adjunct, Jeddah 21413, Saudi Arabia
来源
关键词
epoxy; soybean oil; cure kinetics; isothermal; differential scanning calorimetry; EPOXIDIZED SOYBEAN OIL; CURING KINETICS; MECHANICAL-PROPERTIES; SYSTEM; COMPOSITES; ETHER; MODEL;
D O I
10.1002/cjce.22504
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study presents the kinetics of the reaction of diglycidyl ether of bisphenol A (DGEBA) based epoxy resin in the presence of epoxidized soybean oil (ESO) cured with triethylene tetramine (TETA). An isothermal differential scanning calorimetric (DSC) study is carried out to propose a model to analyze the cure kinetics of bio-based resin. The proposed model is also compared with the Kamal model. The results clearly highlight that the proposed model attains a reasonable percentage of improvement in predicting cure data. Adding ESO to the conventional system decreases the reaction enthalpy and increases the activation energy of the system. The outcome of the study confirms the feasibility of the proposed material system for an infusion process. Further, tensile property improvement is obtained through using an infusion process for the proposed material system.
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页码:1375 / 1380
页数:6
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