New semiconducting core-shell nanocomposites

被引:17
|
作者
Al-Hussaini, A. S. [1 ]
El-Bana, W. E. [1 ]
El-Ghamaz, N. A. [2 ]
机构
[1] Port Said Univ, Fac Sci, Chem Dept, 23 December St, Port Said 42521, Egypt
[2] Damietta Univ, Fac Sci, Phys Dept, Dumyat, Egypt
关键词
Polycondensation; gamma-nano-Al2O3; core-shell; semiconductive polymer nanocomposites; TEM; antimicrobial activity; NONCONVENTIONAL SYNTHESIS; ELECTRICAL-PROPERTIES; ANTHRANILIC ACID; POLYANILINE; FABRICATION; PARTICLES; TERPOLY(ANILINE; NANOPARTICLES; COMPOSITES; COPOLYMER;
D O I
10.1080/09276440.2019.1637237
中图分类号
TB33 [复合材料];
学科分类号
摘要
The present work describes a remarkable synthetic interest of semiconducting core-shell nanocomposites (CSNCs) contained aluminum oxide. Al2O3@poly(aniline -co- o-phenylenediamine) (Al2O3@PANI-o-PDA) CSNCs were fabricated by fivefold molar ratio of the appropriate moieties with various quantities of gamma-Al2O3 by oxidative polymerization. The formation of the Al2O3@PANI-o-PDA CSNCs was confirmed by spectral characteristics. The nanocomposite core-shell feature was found cores thickness 38 nm and shells thickness 41-44 nm. The recorded sigma(dc) is 2.9 x 10(-8)-1.45 x 10(-7) ohm(-1) m(-1) being in the range of semiconductor materials at room temperature and increases with increasing temperature. The newly fabricated materials were investigated as antimicrobial agents. The setup presents a facile, cheap, novel and beneficial methodology to develop novel CSNCs acquiring the required numerous functionality.
引用
收藏
页码:385 / 399
页数:15
相关论文
共 50 条
  • [1] Synthesis, characterization and antibacterial effect of new magnetically core-shell nanocomposites
    Allafchian, Alireza
    Bahramian, Hamid
    Jalali, Seyed Amir Hossein
    Ahmadvand, Hossein
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2015, 394 : 318 - 324
  • [2] Towards Appraising Influence of New Economical Polymeric Core-Shell Nanocomposites
    Al-Hussaini, Ayman S.
    Mohamedein, Abdullah M.
    Hassan, Mohamed E. R.
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2021, 31 (04) : 1491 - 1502
  • [3] SYNTHESIS AND CHARACTERIZATION OF CORE-SHELL TaNx NANOCOMPOSITES
    Liu, Lianyun
    Huang, Kai
    Wang, Zheng
    Hou, Jungang
    Zhu, Hongmin
    [J]. TMS 2012 141ST ANNUAL MEETING & EXHIBITION - SUPPLEMENTAL PROCEEDINGS, VOL 2: MATERIALS PROPERTIES, CHARACTERIZATION, AND MODELING, 2012, : 59 - 66
  • [4] INTERFACIAL EFFECTS IN CORE-SHELL POLYMER NANOCOMPOSITES
    Pissis, Polycarpos
    Klonos, Panagiotis
    Kyrists, Apostolos
    Gun'ko, Vladimir M.
    [J]. 20TH INTERNATIONAL CONFERENCE ON COMPOSITE MATERIALS, 2015,
  • [5] Cerium dioxide/polyaniline core-shell nanocomposites
    Chuang, Feng-Yi
    Yang, Sze-Ming
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 320 (01) : 194 - 201
  • [6] Magnetoelectric properties of core-shell particulate nanocomposites
    Islam, Rashed A.
    Bedekar, Vishwas
    Poudyal, Narayan
    Liu, J. Ping
    Priya, Shashank
    [J]. Journal of Applied Physics, 2008, 104 (10):
  • [7] Core-Shell Structured Nanocomposites with Electromagnetic Properties
    Wang, Xichang
    Li, Xin
    [J]. CURRENT TRENDS IN THE DEVELOPMENT OF INDUSTRY, PTS 1 AND 2, 2013, 785-786 : 607 - 612
  • [8] Titanium oxide and polyaniline core-shell nanocomposites
    Chuang, FY
    Yang, SM
    [J]. SYNTHETIC METALS, 2005, 152 (1-3) : 361 - 364
  • [9] Core-shell magneto-luminescent nanocomposites
    Matiushkina, A. A.
    Baranov, M. A.
    Dubavik, A. U.
    Orlova, A. O.
    [J]. NANOPHOTONICS VIII, 2021, 11345
  • [10] Magnetoelectric properties of core-shell particulate nanocomposites
    Islam, Rashed A.
    Bedekar, Vishwas
    Poudyal, Narayan
    Liu, J. Ping
    Priya, Shashank
    [J]. JOURNAL OF APPLIED PHYSICS, 2008, 104 (10)