A-type procyanidins from Litchi chinensis pericarp with antioxidant activity

被引：106

作者：

Liu, Liang ^{[1
]}

Xie, Bijun ^{[1
]}

Cao, Shaoqlan ^{[1
]}

Yang, Erning ^{[1
]}

Xu, Xiaoyun ^{[1
]}

Guo, Shanshan ^{[1
]}

机构：

[1] Cent China Agr Univ, Food Sci & Technol Coll, Wuhan 430070, Peoples R China

来源：

FOOD CHEMISTRY | 2007年 / 105卷 / 04期

关键词：

litchi; procyanidins; identification; antioxidant activity;

D O I：

10.1016/j.foodchem.2007.05.022

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The main oligomeric procyanidins from litchi pericarp, (Litchi chinensis) were isolated and identified. Complete assignment of epicatechin-(4 beta -> 8, 2 beta -> O -> 7)-epicatechin-(4 beta -> 8)-epicatechin structure was obtained using CD, NMR and ESI-MS techniques. The known (-)-epicatechin and procyanidin A2 were also isolated from litchi pericarp. The effects of oligomeric procyanidins, A2 and epicatechin-(4 beta -> 8, 2 beta -> O -> 7)-epicatechin-(4 beta -> 8)-epicatechin from litchi pericarp on free radical-scavenging were determined by using a chemiluminescent method. The results showed that all of them had a strong scavenging effect on 'OH, and the IC50 values were 2.60 mu g/ml, 1.75 mu g/ml and 1.65 mu g/ml for oligomeric procyarridins, A2 and the trimeric procyanidins, respectively. The antioxidant activities of A-type dimeric and trimeric procyanidins seemed to be related to the number of hydroxyls in their molecular structures. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：1446 / 1451

页数：6

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