Diastereoselective Synthesis of Pyranoquinolines on Zirconium Containing UiO-66 Metal-Organic Frameworks

被引：44

作者：

Rechac, Victor L. ^{[1
]}

Cirujano, Francisco G. ^{[1
]}

Corma, Avelino ^{[1
]}

Llabres i Xamena, Francesc X. ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, Consejo Super Invest Cient, Ave Naranjos S-N, E-46022 Valencia, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 27期

关键词：

Metal-organic frameworks; Heterogeneous catalysis; Zirconium; Diastereoselectivity; Cycloaddition; Nitrogen heterocycles; DIELS-ALDER REACTIONS; STEREOSELECTIVE-SYNTHESIS; HETEROGENEOUS CATALYST; CONVENIENT SYNTHESIS; ACID; DERIVATIVES; QUINOLINES; EFFICIENT; MOFS;

D O I：

10.1002/ejic.201600372

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Zr terephthalate MOFs UiO-66 and UiO-66-NH2 have been found to be highly diastereoselective catalysts for the synthesis of a pyrano[3,2-c]quinoline through an inverse electron -demand aza-Diels-Alder [4+2] cycloaddition of an aryl Qmine (formed in situ from aniline and benzaldehyde) and 3,4-dihydro-2H-pyran in one pot, affording the corresponding trans isomer in diastereomeric excesses of 90-95 %. The solids are stable under the reaction conditions and can be reused at least three times without significant loss of activity or diastereoselectivity.

引用

页码：4512 / 4516

页数：5

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